Ok several things.
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I purchased my first ball python last week. I got him home, set up his cage, and left him alone for a day.
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You should give a new snake at least a week to settle in.
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When an animal does not display behavior common to the species, to me thats a red flag.
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The snake not constricting is NOT a sign of problematic behavior. Many snakes do not constrict pinkies or fuzzies, even if they are alive! The snake seems to know that they are harmless and I have seen snakes in the wild swallow pinkies alive! I have also seen snakes swallowing frogs while still alive. Your snake is fully capable of constricting should the need be there.
Freezing has nothing to do with vitamin D. What you are thinking of is thamine. Vitamine B. Freezing vegetables will destroy Thiamin over a period of time. There are countless generations of snakes that have been fed exclusively on frozen. In fact most of the reptiles housed in zoos are on a frozen diet.
There is no reason to switch a snake that is eating frozen to live prey. You will be backpedaling from what you need to do. Many snakes have been severely injured and even killed by what was intended to be their dinner!
Your temps do indeed need to come up. Aim for a basking spot of about 90-95 degrees. Your humidity can fluctuate. It does in the wild. There are dry periods and wet periods. 100% humidity is too high. In fact if you maintained 100% humidity for any length of time you would have a wonderful garden of mold, fungus and other nasties! You do want to raise it when the snake is in shed.
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The hoppers are a bit bigger than the fuzzies, approximately 1.5 times as large as the snakes head.
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The rule is 1 to 1 1/2 times the diameter of the snake's BODY at the widest part, not the head.
It is not uncommon for a snake that is being fed prey that is on the small size to swallow it backwards,. I have even seen them swallow it sideways!
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its more entertaining for owner and snake when the snake constricts its prey. Perhaps all this captive breeding has breed the soul out of the snake. When I do start breeding ball pythons, I will probably want to introduce wild stock into the gene pool so theres no unpleasent mutations likely to show up.
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To be honest the entertainment value lies totally in the realm of the keeper. The snake doesn't care one way or another. All it is concerned with is food! In other words you would be risking the snake's safety for YOUR amusement. And you may be surprised to know tha the vast majority of Ball python hatchlings available are NOT captive BRED but captive HATCHED. These babies were hatched from eggs taken from wild stock.